程津培  教授,中科院院士

基础分子科学中心主任

 

研究方向:

物理有机化学
有机能量学
化学键键能的测定与计算

程津培,有机化学家,中国科学院院士(2001),第三世界科学院院士(TWAS,2001),清华大学基础分子科学中心主任(2012)。1975年毕业于天津师范学院,1981年获南开大学硕士,1987年获美国西北大学博士,1988年到南开大学工作(1995-2000年任副校长),2000-2008年担任国家科技部副部长。现任全国人大常委、教科文卫委员会副主任、致公党中央副主席、国家教育咨询委员会委员、国家科技奖励委员会委员、欧美同学会副会长等职。

程津培教授主要从事物理有机化学研究,主要研究课题包括有机溶剂中各类化学键键能的方法学和实验测定、自由基稳定性理论、一氧化氮(NO)转移的热力学驱动力和机理、NADH辅酶模型的反应的热力学,动力学及机理、负氢热力学、叶立德(Ylide)稳定性的统一标度、离子液体中化合物pKa测定和有机小分子催化不对称有机反应机理等。

程津培教授在Science,Angewandte Chemie Internal Edition,Journal of the American Chemistry Society,The Journal of Organic Chemistry,Organic Letters,Chemistry - an European Journal,Chemical Communications等国内外著名刊物上发表了学术论文200余篇。这些论文已被国际论文他引5000余次,其中单篇最高他引达200余次。2005年获得何梁何利科学与技术进步奖。

 

代表性论文

  1. Wang, Z.-D.; Li, X.; Ji, P.*; Cheng, J.-P.* Absolute pKas of Sulfonamides in Ionic Liquids: Comparisons to Molecular Solvents. J. Org. Chem. 2016, 81, 11195.
  2. Mao, C.; Wang, Z.-D.; Wang, Z.; Ji, P.*; Cheng, J.-P.* Weakly Polar Aprotic Ionic Liquids Acting as Strong Dissociating Solvent: A Typical “Ionic Liquid Effect” Revealed by Accurate Measurement of Absolute pKa of Ylide Precursor Salts. J. Am. Chem. Soc. 2016, 138, 5523.
  3. Mao, C.; Wang, Z.; Ji, P.*; Cheng, J.-P.* Is Amine a Stronger Base in Ionic Liquid Than in Common Molecular Solvent? An Accurate Basicity Scale of Amines. J. Org. Chem. 2015, 80, 8384.
  4. Wang, Z.; Ji, P.*; Li, X.; Cheng, J. -P.* Double-Line Hammett Relationship Revealed through Precise Acidity Measurement of Benzenethiols in Neat Ionic Media: A Typical “Ionic Liquid Effect?” Org. Lett. 2014, 16, 5744.
  5. Xue, X.; Li, X.; Yu, A.; Yang, C.; Song, C.; Cheng, J.-P. Mechanism and Selectivity of Bioinspired Cinchona Alkaloid Derivatives Catalyzed Asymmetric Olefin Isomerization: A Computational Study J. Am. Chem. Soc. 2013, 135, 7462-7473.
  6. Deng, H.; Li, X.; Chu, Y.; He, J.; Cheng, J.-P. Standard pKa Scales of Carbon-Centered Indicator Acids in Ionic Liquids: Effect of Media and Structural Implication J. Org. Chem. 2012, 77, 7291-7298.
  7. Liu, C.; Tan, B.-X.; Zhang, Y.-Y.; Jin, J.-L.; Dong, N.; Li, X.; Cheng, J.-P. Chiral Biscinchona Alkaloid Promoted Asymmetric Allylic Alkylation of 3-Substituted Benzofuran-2(3H)-ones with Morita–Baylis–Hillman Carbonates J. Org. Chem. 2011, 76, 5838-5845.
  8. Fu, N.-K.; Zhang, L.; Li, J.-Y.; Luo, S.-Z.; Cheng, J.-P. Chiral Primary Amine Catalyzed Enantioselective Protonation via an Enamine Intermediate Angew. Chem. Int. Ed. 2011, 50, 11451-11455.
  9. Lv, J.; Zhang, L.; Zhou, Y.-M.; Nie, Z.-X.; Luo, S.-Z.; Cheng, J.-P. Asymmetric Binary Acid Catalysis: A Regioselectivity Switch between Enantioselective 1,2- and 1,4-Addition through Different Counteranions of InIII Angew. Chem. Int. Ed. 2011, 50, 6610-6614.
  10. Zheng, X.-X.; Zhang, L.; Li, J.-Y.; Luo, S.-Z.; Cheng, J.-P. Magnetic Nanoparticle Supported Polyoxometalates (POMs) via Non-Covalent Interaction: Reusable Acid Catalysts and Catalyst Supports for Chiral Amines Chem. Commun. 2011, 47, 12325-12327.

办公室:
蒙民伟科技楼南楼S-901室

电子邮件:
jinpei_cheng
@mail.tsinghua.edu.cn

联系电话:
010-6279 6217