程津培教授课题组研究助理
离子液体中的键能研究
离子液体的溶剂化效应
化学键的活化策略
吉鹏举,1976年10月出生于陕西延安。本科,硕士毕业于西北大学化学系。2005至2008年工作于天津大学石油技术开发中心,任职助理研究员。博士毕业于英国University of Huddersfield (2011, 导师:Prof. Mike Page and John Atherton),对液氨中的一些个基本有机反应的机理,如SN2, SNAr以及芳基卤代物的直接胺化机理进行了系统研究。 2012年至2014年清华大学化学系博士后,合作导师为程津培院士。2015年留校加入基础分子科学中心程津培院士科研团队。现阶段主要研究方向为离子液体中有机化合物键能研究以及离子液体的溶剂化效应;有机化学键活化的一般策略的探索研究。
近五年代表性论文:
1. Wang, Z.; Wang, F.; Xue, X.-S.*; Ji, P.* Acidity Scale of N-Heterocyclic Carbene Precursors: Can We Predict the Stability of NHC-CO2 Adducts? Org. Lett. 2018, 20, 6041.
2. Yang, J.-D.+; Ji, P.+; Xue, X.-S.; Cheng, J.-P.* Recent Advances and Advisable Applications of Bond Energetics in Organic Chemistry. J. Am. Chem. Soc. 2018, 140, 8611. [Perspective]
3. Wang, Z.; Gao, F. X.; Ji, P.*; Cheng, J.-P.* Unexpected Solvation-stabilisation of Ions in a Protic Ionic Liquid: Insights Disclosed by a Bond Energetic Study. Chem. Sci. 2018, 9, 3538.
4.Xue, X.-S.+; Ji, P.+; Zhou, B.; Cheng, J.-P.* The Essential Role of Bond Energetics in C–H Activation/Functionalization. Chem. Rev. 2017, 117, 8622.
5. Mao, C.; Wang, Z.-D.; Wang, Z.; Ji, P.*; Cheng, J.-P.* Weakly Polar Aprotic Ionic Liquids Acting as Strong Dissociating Solvent: A Typical “Ionic Liquid Effect” Revealed by Accurate Measurement of Absolute pKa of Ylide Precursor Salts. J. Am. Chem. Soc. 2016, 138, 5523.
6. Mao, C.; Wang, Z.; Ji, P.*; Cheng, J.-P.* Is Amine a Stronger Base in Ionic Liquid Than in Common Molecular Solvent? An Accurate Basicity Scale of Amines. J. Org. Chem. 2015, 80, 8384.
7. Wang, Z.; Ji, P.*; Li, X.; Cheng, J. -P.* Double-Line Hammett Relationship Revealed through Precise Acidity Measurement of Benzenethiols in Neat Ionic Media: A Typical “Ionic Liquid Effect”? Org. Lett. 2014, 16, 5744.